Once employed, the employee usually fills out an employee form that he needs to fill out with the information requested. An employee form template would normally look like a form with the name of the company on top, and a title stating New Employee Form.
Now, you have thousands of free document templates that can be turned into web forms. What you need is, open MS word. Then you will need to go to your title bar and move to file. Here you have several existing templates to choose from. You can choose anyone among them and modify them according to your needs. Apart from changing the forms, you can start with a scrap or, blank template.